Re: [RML] Calcium solution question

Michael F. Adams Jr. (mfadam1 at pop.uky.edu)
Thu, 18 Dec 1997 11:15:44 -0500

Lexington gets its water from a single pumping station. The source water
comes from the Kentucky River. This area of the country sits on limestone
which explains why there is a predominance of calcium in our water. Now,
one thing I've noticed with the reef blocks (HBH Balance Blocks) it that
they never seem to completely dissolve. I figured this was probably the
calcium that cannot dissolve into the water because it's already essentially
saturated. But, I've continued using them figuring the other trace elements
in there are doing some good. I've never had any fry develop deformed fins,
but this doesn't mean it can't happen here. I'm pretty sure that Mark
hasn't had any problems with deformed fins either, but we could ask him. I
know he doesn't use any blocks with his fry. That doesn't mean that these
block don't do any good in other parts of the world, but I agree with you,
Gary, that from a calcium standpoint, they probably don't add anything to
the environment. But I figure why not put them in there anyway. I do wish,
however, that they'd include the "trace elements" that come with them.

Cheers.

Mike

At 10:54 PM 12/16/97 -0600, you wrote:
><snip>
>...so I bought a calcium test kit. What I discovered is my
>> calcium level is less than 20ppm in my tap water. So though it was
>> very hard water, most of the hardness was not cause by calcium.
>>
>> Generally I have torn down an 10 gallon tank and totally replaced the
>> water before adding a mop of eggs. I'll then drop in the mop and one
>> HBH balance block. With Melanotaenia, if I have fry with in 24 hours I
>> get deformed fry. Fry born after this period do not have the fin
>> deformities exhibited by these early born fry. I have yet to actually
>> measure the level of calcium added by the balance block in 24 hours,
>> but it is obvious that not enough has dissolved to supply the needs of
>> the fry.
>> I have now began adding calcium chloride to the water, rather than
>> waiting for the balance blocks to dissolve. I feel this should give me
>> better control over calcium levels without the lag time waiting for
>> the blocks to dissolve.
>Cary what is the KH of this designed water?
>After playing with the reef blocks a few times I reached the same conclusions -
>the calcium wasn't available fast enough nor at reliable hardness
>concentrations. Besides everything else, compared to calcium chloride, which
>can be bought at the hardware store (ice-melt) it is very expensive. With
>calcium chloride you just add a certain amount, dissolve it and you're
>finished. I would make sure of your hardness before you go adding anything
>willy-nilly. For instance Mike Adams mentioned that he used reef blocks in his
>set up to add calcium to the water. Perhaps not all of Lexington KY is on the
>same water system but the water I measured was 233 ppm (~ 13 drops GH). When I
>remeasured with a calcium specific hardness kit (Wardley Professional Test Kit)
>it was 100% calcium, not a single bit of magnesium hardness to be found! That
>surprised me so much that I repeated both tests. Most public water systems
>that I've tested are usually 50:50 magnesium to calcium. Mike if your water is
>the same I would suggest that you aren't doing your fry a lot of good with the
>blocks. You might be better off adding a bit of baking soda though, the KH of
>Lexington is only 2 degrees (36 ppm) hardness. About 1/2 teaspoon/10 gallons
>will increase your carbonate hardness about 2 degrees. but.... don't go too
>overboard.
>
>Now how the H*** does all of this calcium/magnesium compare to what we see in
>nature? Cary, did you see this deformity happen with any Australian rainbows?
>I think I have seen it with some trifasciatas. It sounds like quite a few of
>the NG fish come from harder water. Some of the other numbers I wouldn't mind
>rechecking myself. Some creeks like Harvey's creek are incredibly soft,
>essentially 0 degrees GH and KH, pH pretty low too. (springtime, October
>measurements). Many of Bruce's measurements also showed these low values. So
>how do those fish survive and not all have these fin deformities that we
>observe in our aquariums?
>
>My "theory" is that it's a balance between carbonate (KH) and GH (specifically
>Calcium). Too much carbonate compared to Calcium and you end up with deformed
>fins. My water is 7-8 degrees general hardness GH (about 125-143 ppm). About
>1/2 of that is calcium (3.5-4 degrees hardness). My KH, carbonate hardness is
>usually around 2 degrees. I normally never have a problem with fin deformities
>unless I really abuse the tank by not doing any water changes. I managed to do
>that 2 times in about 10 years so it wasn't an everyday occurrence. About a
>year or so I started adding enough baking soda to increase the carbonate
>hardness by about 2 degrees. (I did this so I would have a more stable pH as
>my pH can crash to 5.5 within a few week without a water change). All of a
>sudden I started seeing lots of fry with deformed fins. I didn't change
>anything in how I was raising fry except for the carbonate value. My carbonate
>value was somewhat equal or greater than my calcium hardness value. I managed
>to do this to M. papuae and M. trifasciata, canoe creek. I had a few others
>too that I trashed right away, happy coal grunter, sad owner. I then started
>playing with the calcium blocks and then settled on the more reliable calcium
>chloride. I moved my (calcium), GH hardness up about 7 degrees (108 ppm) by
>adding 1/2 teaspoons (2.5cc) of calcium chloride per 4 gallons. After that
>I've had absolutely no problems with deformed fins on my fry. I think that a
>calcium/carbonate balance ratio is the easiest way to explain away this
>problem. Otherwise you have to start doing a lot of handwaving in trying to
>explain why it doesn't happen to fry in their native waters. Some have
>proposed theories about vitamin deficiencies, not the right type of live foods
>etc., but I think that's probably reaching too much. This theory would also
>suggest why coral/shell grit might not work very well, especially in a fairly
>crowded tank. For each bit of calcium you would also be getting an equal
>amount of carbonate.
>
>My request to you, especially if you've had problems with deformed fins on your
>fry. What is/was the general hardness of your water? If you have a calcium
>test kit what percentage of that general hardness is actually calcium? What is
>the KH of your water?
>
>
>
------------------------------
Michael F. Adams Jr.
Graduate Studies in Transportation/Environmental Engineering
College of Engineering--Traffic Lab
C216 CE/Trans Building
University of Kentucky
Lexington, Kentucky
606/257-4349